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A Fully Coupled Three-Dimensional Dynamic Model of Polymeric Membranes for Fuel Cells

P. Alotto[1], M. Guarnieri[1], and F. Moro[1]

[1]Dipartimento di Ingegneria Elettrica, Università di Padova, Padova, Italy

The proton exchange membrane is a key component in the currently widely studied Proton Exchange Membrane Fuel Cells. In this paper a fully coupled three-dimensional dynamic numerical model of the membrane including all the physically relevant phenomena, i.e. ion transport, hydration-dependent conductivity and thermal effects is presented. The highly non-linear model is discretized by means of ...

Numerical and Experimental Study of Flow, Heat Transfer and Concentration in a Scaled-up Fuel Cell Anode Channel Model

J. C. Torchia-Nüñez[1], and J.G. Cervantes-de-Gortari[1]

[1]Department of Thermal Engineering, National University of Mexico, UNAM, Mexico City, Mexico

Flow, concentration and temperature fields are studied with numerical and experimental methods inside a scaled-up fuel cell anode channel model. The low aspect ratio channel has a porous medium as the inferior wall where a mixing of different pH solutions occurs. Chromatic change of phenolphthalein is used to visualize concentration field and Particle Image Velocimetry (PIV) is used to visualize ...

Modeling of the Transport Phenomena in Lithium-Ion Battery Electrolytes

A. Nyman, M. Behm, and G. Lindbergh
Applied Electrochemistry, School of Chemical Science and Engineering, Royal Institute of Technology Stockholm, Sweden

Modeling of mass transport is an important step in evaluating lithium-ion battery electrolytes and understanding cell performance. For high-power applications, concentration gradients in the electrolyte lead to limiting currents, which limit the power-density of the battery. The model has been used for determining a complete set of transport and thermodynamic properties for LiPF6 dissolved in an ...

Multiphysics Simulation of an Anode-supported Micro-tubular Solid Oxide Fuel Cell (SOFC)

G. Ganzer, W. Beckert, T. Pfeifer, and A. Michaelis
Fraunhofer IKTS
Dresden, Germany

The high thermal stability and fast start-up behavior make micro-tubular solid oxide fuel cells (SOFCs) a promising alternative for small-scale, mobile power devices in the range of some Watts. To understand the transport phenomena inside a single micro-tubular SOFC, a 2-D, axi-symmetric, non-isothermal model, performed in COMSOL Multiphysics® 4.2, has been developed. Due to long current path ...

Fluid Flow and Current Density Distribution in Large-area HT PEMFCs

G. C. Bandlamudi[1,2], C. Siegel[2], C. Heßke[1], and A. Heinzel[1,2]
[1]ZBT Duisburg, Duisburg, Germany
[2]University of Duisburg-Essen, Duisburg, Germany

High temperature polymer electrolyte membrane fuel cells (HT PEMFCs) are very promising technologies when used in combined cooling and heating power (CCHP) systems. They are operated at 160°C, offering the possibility of high tolerance to fuel impurities and a possibility to use the heat generated for cooling and heating purposes, leading to higher total system efficiency. Employing a 24 ...

Constructing COMSOL Models of a Bacteriological Fuel Cell

R. Coker[1], J. Mansell[1]
[1]NASA - Marshall Space Flight Center, Huntsville, AL, USA

We have started constructing preliminary design COMSOL models of a bacteriologically driven \'fuel cell\' that is intended to process waste products, such as carbon dioxide and brine, from a crewed vehicle. At this early stage, this complex system is reduced to two electrodes separated by a membrane. The electrolyte is a brine appropriate for growing methanogenic bateria, though none are ...

Evaluation of Performance of Enzymatic Biofuel Cells with Microelectrode Arrays Inside a Blood Artery via Finite Element Approach

C. Wang[1], Y. Song[1]
[1]Florida International University, Miami, FL, USA

Enzymatic biofuel cells (EBFCs) are considered as a promising candidate for powering miniature implantable devices. In order to predict the performance in the human blood artery, we simulated a 3D EBFC chip with highly dense micro-electrode arrays. In this simulation using COMSOL Multiphysics®, we applied the 1) Michaelis Menten equation; 2) Nernst potential equation; 3) Navier Strokes velocity, ...

Advanced 3D Imaging Coupled to Modeling of Fuel Cell and Battery Electrodes

F. Tariq[1], V. Yufit[1], M. Marinescu[1], G. Cui[1], M. Kishimoto[1], N. Brandon[1]
[1]Imperial College London, London, United Kingdom

Solid Oxide Fuel Cells (SOFC) and Li-ion batteries (LIB) are electrochemical devices where performance is dependent on reactions inside porous electrode microstructures. Here we use tomographic techniques to probe 3D electrode structures (anodes and cathodes) at micro-nanometer length scales. Subsequently, micro/nano structural changes in electrodes are characterized and quantified. Utilizing ...

Numerical Simulation of Carbon Steel Corrosion Exposed to Flowing NaCl Solutions Through an Annular Duct - new

A. Soliz[1], K. Mayrhofer[1], L. Caceres[2]
[1]Department of Interface Chemistry & Surface Engineering, Max-Planck-Institut für Eisenforschung, Düsseldorf, Germany
[2]Department of Chemical Engineering, University of Antofagasta, Antofagasta, Chile

A three-dimensional mathematical model under stationary conditions have been established to understand the corrosion of carbon steel cylindrical samples immersed in flowing NaCl solution through an annular duct. The migration, diffusion and convection mass transfer mechanisms were solved using the Nernst–Planck equation coupled to the Navier-Stokes equation. A corrosion model based on the mixed ...

Stresses Due to Intercalation of Non-Spherical Lithium Storage Particles - new

R. Purkayastha[1], R. McMeeking[2]
[1]Cambridge University, Cambridge, UK
[2]University of California, Santa Barbara, CA, USA

Due to computational considerations most models of lithium storage particles in batteries incorporate spherical particles. However most storage particles used in battery electrodes tend to be irregular in shape with sharp edges and extended aspect ratios. The change of the relative surface area to the volume of the particle can lead to a change in the stress response of the particle for the same ...