Screening Effects in Probing the Electric Double Layer by Scanning Electrochemical Potential Microscopy
R.F. Hamou, P.U. Biedermann, A. Erbe, and M. Rohwerder
Max-Planck-Institut für Eisenforschung GmbH, Düsseldorf, Germany
A computational method is developed to study probing the electric double layer by Scanning Electrochemical Potential Microscopy. The model is based on a modified Poisson- Boltzmann equation, which takes into account steric effects. We investigated the effect of metallic apex protrusion and the Open Circuit Potential (OCP) of the tip on the probed potential. A clear electrostatic screening effect ...
B. Bozzini, S. Maci, I. Sgura, R. Lo Presti, and E. Simonetti
Dipartimento di Ingegneria dell’Innovazione, Università del Salento, Lecce, Italy
Dipartimento di Matematica, Università del Salento, Lecce, Italy
ENEA Casaccia, Dipartimento TER, Centro Ricerche Casaccia, S. Maria di Galeria, Roma, Italy
This paper describes the numerical modeling of a key material-stability issue within the realm of Molten Carbonate Fuel Cells (MCFC). The model describes the morphological and attending electrocatalytic evolution of porous NiO electrodes and is apt to predict electrochemical observables that can be recorded during Fuel Cell operation. The model has been validated with original experimental data ...
P. Fodor, and J. D'Alessandro
Dept. of Physics
Cleveland State University
In this work a miniaturized fuel cell design based on microchannels, into which the liquid fuel and oxidizer streams are fed through T shaped connectors, is optimized for improved fuel usage. This particular design exploits the laminar nature of the fluid flow at small Reynolds numbers to keep the fuel and oxidizer confined in the vicinity of the corresponding electrodes without the need of a ...
Simulating the Influence of the Nozzle Diameter on the Shape of Micro Geometries Generated with Jet Electrochemical Machining
A. Schubert, M. Hackert, and G. Meichsner
Chair Micromanufacturing Technology, Faculty of Mechanical Engineering, Chemnitz University of Technology, Chemnitz, Germany
Fraunhofer Institute for Machine Tools and Forming Technology, Chemnitz, Germany
Jet Electrochemical Machining (Jet-ECM) is an unconventional procedure for micromachining. Based on localized anodic dissolution three-dimensional geometries and microstructured surfaces can be manufactured using Jet-ECM. COMSOL Multiphysics is used at Chemnitz UT to simulate the electric current density in the jet and the dissolution process. A mesh displacement dependent on the normal current ...
TVS Motor Company Ltd., Hosur, Tamil Nadu, India
The proposed State of Charge (SOC) governed fast charging method for secondary lithium based batteries charges a battery many times faster than the normal Constant Current-Constant Voltage (CC-CV) charging and reduces the side-effects generally accompanied by various fast charging methods. The proposed charging algorithm takes into account the varying internal impedance of the battery at ...
SRI International, Menlo Park, CA, USA
Iouri Balachov is a Senior Scientist at SRI International (Menlo Park, CA) where he is leading development of Direct Carbon Fuel Cell technology for clean and efficient power generation from coal, biomass, and a wide variety of carbon containing fuels. Prior to SRI he was an engineer at Westinghouse nuclear (Pittsburgh, PA), researcher at Penn State University (State College, PA), and researcher ...
H. Kwon, and E. Akyiano
Dept. of Engineering and Computer Science
Berrien Springs, MI
In this paper, the cyclic voltammetry behavior of Ferrocyanide/Ferricyanide, which is commonly used for electrochemical DNA detection experiment, was studied in the commercial EQCM-D setup (Q-sense) using the COMSOL Multiphysics. The model was established in a 3D geometry of QCM liquid cell. The simulation shows depletion of concentration of ferrocyanice following applied electrode ...
F. Lima, U. Mescheder, H. Reinecke
Hochschule Furtwangen University, Furtwangen, Baden-Wuerttemberg, Germany
Institut für Mikrosystemtechnik, Freiburg im Breisgau, Baden-Wuerttemberg, Germany
Electrodeposition has a major advantage over other methods of thin film deposition. It allows deposition at atmospheric pressure and room temperature, requiring inexpensive equipment. However, there are several parameters which can influence an electroplated metal layer quality. The current density distribution is taken into consideration. The Hull cell is an electrodeposition tank with a ...
SPAWAR Systems Center (SSC) ATLANTIC, Charleston, SC, USA
Additive manufacturing uses 3D printing to build physical parts from CAD-based designs. The technology includes fused deposition modeling (FDM) and selective laser sintering (SLS) methods. 3-D printing is of particular interest for smaller, one-of-a-kind, customizable products. A cube satellite (CubeSat) containing fiber reinforced SLS parts has been successfully launched (Ref 1). Lower ...
Finite Element Analysis of an Enzymatic Biofuel Cell: The Orientations of a chip inside a blood artery
C. Wang, Y. Parikh, Y. Song, and J. Yang
Mechanical & Materials Science Engineering, Florida International University, Miami, Florida, USA
Output performance of an implantable enzymatic biofuel cell (EBFC) with three- dimensional highly dense micro-electrode arrays has been simulated with a finite element analysis approach. The purpose of this research is to optimize the orientation of this EBFC chip inside a blood artery such that the mass transport of glucose around all the micro-electrodes can be improved and hence output ...